AI Article Synopsis
- The compound C(9)H(10)N(2)O(2) has 13 non-hydrogen atoms that are nearly planar, with slight deviations influenced by oxygen atoms.
- An intra-molecular hydrogen bond between the hydroxyl and nitrogen stabilizes its conformation, which features an E configuration around the N=C double bond.
- Additionally, inter-molecular hydrogen bonds form between the hydroxyl and carbonyl oxygen atoms, creating a flat double-layer structure that stacks along the a-axis, facilitated by C-H⋯π interactions.
Article Abstract
The 13 non-H atoms comprising the title compound, C(9)H(10)N(2)O(2), are close to planar (r.m.s. deviation = 0.140 Å), with maximum deviations of 0.292 (1) and 0.210 (1) Å to either side of the least-squares plane exhibited by the hy-droxy and carbonyl O atoms, respectively. The observed conformation is stabilized by an intra-molecular O-H⋯N hydrogen bond. The conformation about the N=C double bond [1.2909 (16) Å] is E. The hy-droxy OH group also forms an inter-molecular hydrogen bond to a carbonyl O atom, and the amine H atom similarly forms an N-H⋯O hydrogen bond to a second carbonyl O atom. The result is the formation of a double layer with a flat topology. Layers stack along the a-axis direction connected by C-H⋯π inter-actions.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089133 | PMC |
| http://dx.doi.org/10.1107/S1600536811013717 | DOI Listing |
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