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rac-2,2'-(Thiane-2,6-di-yl)bis-[1-(4-bromo-phen-yl)ethanone]. | LitMetric

rac-2,2'-(Thiane-2,6-di-yl)bis-[1-(4-bromo-phen-yl)ethanone].

Acta Crystallogr Sect E Struct Rep Online

College of Chemistry and Chemical Engineering, Graduate University of Chinese, Academy of Sciences, Beijing, 100049, People's Republic of China.

Published: May 2011

In the title compound, C(21)H(20)Br(2)O(2)S, prepared by the reaction of 1,9-bis-(4-bromo-phen-yl)nona-2,7-diene-1,9-dione with sodium sulfide nona-hydrate in acetonitrile, the six-membered thio-pyran ring has a chair conformation while the H atoms ortho to the S atom adopt a cis configuration. The dihedral angle between the two benzene rings is 2.59 (8)°.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089314PMC
http://dx.doi.org/10.1107/S1600536811011792DOI Listing

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