In the title compound, C(11)H(11)N(5)OS, the pyrazole ring is approximately planar, with a maximum deviation of 0.010 (2) Å. The dihedral angles between the benzene ring and the pyrazole and carbothio-amide groups are 5.42 (9) and 10.61 (18)°, respectively. An intra-molecular N-H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are connected by inter-molecular N-H⋯O and C-H⋯S hydrogen bonds, forming R(2) (2)(12) ring motifs. In addition, there is a π-π stacking inter-action [centroid-centroid distance = 3.5188 (11) Å] between the pyrazole and benzene rings. These inter-actions link the mol-ecules into infinite chains along [001].

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099837PMC
http://dx.doi.org/10.1107/S1600536811009779DOI Listing

Publication Analysis

Top Keywords

3-methyl-5-oxo-4-2-phenyl-hydrazinyl-idene-45-dihydro-1h-pyrazole-1-carbothio-amide title
4
title compound
4
compound c11h11n5os
4
c11h11n5os pyrazole
4
ring
4
pyrazole ring
4
ring planar
4
planar maximum
4
maximum deviation
4
deviation 0010 2 Å
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!