In the complex anion of the title compound, (C(2)H(6)N(5))[Cu(C(7)H(4)NO(4))(C(7)H(3)NO(4))]·3H(2)O, the Cu(II) atom is coordinated by tridentate 6-carb-oxy-pyridine-2-carboxyl-ate and pyridine-2,6-dicarboxyl-ate ligands and is surrounded by four O atoms in the equatorial plane and two N atoms in axial positions in a distorted octa-hedral geometry. In the crystal, the components are linked into a three dimensional network by O-H⋯O, N-H⋯O, N-H⋯N and C-H⋯O hydrogen bonds and a π-π inter-action with a centroid-centroid distance of 3.6080 (8) Å.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099907PMC
http://dx.doi.org/10.1107/S1600536811011147DOI Listing

Publication Analysis

Top Keywords

35-diamino-4h-124-triazol-1-ium 6-carb-oxy-pyridine-2-carboxyl-atopyridine-26-dicarboxyl-atocuprateii
4
6-carb-oxy-pyridine-2-carboxyl-atopyridine-26-dicarboxyl-atocuprateii trihydrate
4
trihydrate complex
4
complex anion
4
anion title
4
title compound
4
compound c2h6n5[cuc7h4no4c7h3no4]·3h2o
4
c2h6n5[cuc7h4no4c7h3no4]·3h2o cuii
4
cuii atom
4
atom coordinated
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!