The Mn(II) atom in the title complex, [Mn(NCS)(2)(C(14)H(13)NO(2))(2)], lies on a center of inversion in a MnO(4)N(2) octa-hedral geometry. The Schiff base is present in its zwitterionic form and is O,O'-chelated to the metal atom. The imino N atom is protonated and is involved in an intra-molecular hydrogen bond with the phenolate O atom.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099895 | PMC |
http://dx.doi.org/10.1107/S1600536811009330 | DOI Listing |
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