In the title compound, (C(7)H(10)NO)(2)[SnCl(6)], the Sn(IV) atom, located on an inversion center, exists in an octa-hedral coordination environment. The crystal structure exhibits alternating organic and inorganic layers parallel to ([Formula: see text]01). The cations and anions are linked via inter-molecular N-H⋯O, N-H⋯Cl and O-H⋯Cl hydrogen bonds. Additional stabilization is provided by π-π stacking inter-actions between the benzene rings of the cations [centroid-centroid distances = 3.6962 (15) and 3.9340 (15) Å].

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099789PMC
http://dx.doi.org/10.1107/S1600536811007252DOI Listing

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