We describe scanning tunneling microscopy and X-ray photoelectron spectroscopy studies of graphene films produced by sonication-assisted dispersion. Defects in these samples are not randomly distributed, and the graphene films exhibit a "patchwork" structure where unperturbed graphene areas are adjacent to heavily functionalized ones. Adjacent graphene layers are likely in poor mechanical contact due to adventitious species trapped between the carbon sheets of the sample.
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http://dx.doi.org/10.1021/nn1009352 | DOI Listing |
Nanomaterials (Basel)
December 2024
School of Power & Mechanical Engineering, Wuhan University, Wuhan 430072, China.
TiZrMoC coatings were deposited on Si(100) substrates using a DC dual magnetron sputtering. The composition was controlled by adjusting the sputtering parameters of the TiZrMo and graphite targets. The influence of graphite target current on the resulting coating properties was explored.
View Article and Find Full Text PDFNano Lett
December 2024
State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene (NPU), Xi'an 710072, P. R. China.
Dion-Jacobson (DJ) perovskites are promising alternatives for Ruddlesden-Popper (RP) perovskites to fabricate blue perovskite light-emitting diodes (PeLEDs) due to their favorable structural and charge properties. However, the relatively weak hydrogen bond between the bridging diammonium group and perovskite poses huge challenges for regulating crystallization and defect density, leading to an undesirable film quality and device performance. Herein, we report the successful optimization of DJ perovskite films by introducing a new type of cesium octafluoroadipate (CsOFAA) precursor, which could strongly anchor the perovskite through coordination bonds and halogen-halogen bonds.
View Article and Find Full Text PDFHeliyon
December 2024
College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, 010021, China.
Graphene and its derivatives are widely used in various fields due to their unique two-dimensional lamellar structure. This study aims to synthesize ultra-large graphene oxide (GO) sheets from natural flake graphite and investigate the factors influencing their size. Using a two-intercalation method based on the modified Hummers' method, we address the challenge of intercalating large-diameter graphene oxide by employing a secondary intercalation technique.
View Article and Find Full Text PDFFood Chem
December 2024
Sensors and Biosensors Group, Analytical Chemistry and Electrochemistry Lab (LR99ES15), University of Tunis El Manar, Tunis El Manar, 2092 Tunis, Tunisia. Electronic address:
Improper use and harmful effects of nitrite ions pose a significant risk to human health. To address this concern, the use of carbon-based materials for electrochemical sensing is regarded as one of the most promising detection tools for ensuring the quality of drinking water and food products. In this context, we developed laser-ablated graphene electrodes (LAGEs) by direct laser scribing on a polyimide substrate, which were subsequently modified by electrochemical deposition of a redox-active melanin-like film (MeLF/LAGEs).
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Shenzhen institute of advanced technology Chinese Academy of Sciences, Functional Thin Films Research Centre, 1068 Xueyuan Avenue, Shenzhen University Town, 518000, SHENZHEN, CHINA.
Organics electrode materials offer multi-electron reactivity, flexible structures, and redox reversibility, but encounter poor conductivity and durability in electrolytes. To overcome above barriers, we propose a dual elongation strategy of π-conjugated motifs with active sites, involving extended carbazole and electropolymerized crosslinked polymer, which enhances electronic conductivity by the electronic delocalization of electron-withdrawing conjugated groups, boosts theoretical capacity by increasing redox-active site density, and endows robust electrochemical stability attributed to crosslinked organic structures. As a proof-of-concept, 5,11-dihydridoindolo[3,2-b]carbazole (DHIC) is selected as the model cathode material for a dual-ion battery, with elongated carbazole groups functioning both as redox-active centers and polymerization anchors.
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