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Molecular lanthanoid-transition-metal cluster through C-H bond activation by polar metal-metal bonds.
Angew Chem Int Ed Engl
August 2011
Lehrstuhl Anorganische Chemie II, Universität Bayreuth, 95440 Bayreuth, Germany.
Molecules containing rare-earth atoms solely bonded by transition metals.
Nat Chem
September 2010
Lehrstuhl Anorganische Chemie II, Universität Bayreuth, 95440 Bayreuth, Germany.
Although metal-metal bonding is important in the chemistry of both solid-state intermetallic compounds and molecular species, the study of this bonding is limited by the compounds available and it is rarely possible to identify connections between these two areas. In this study, molecular intermetalloids [Ln(ReCp(2))(3)] (Ln = Sm, Lu and La) have been synthesized that contain lanthanoid metals bound only to transition metals. Although they are highly reactive species, such lanthanoid-core transition-metal-shell compounds can be stable in solution.
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