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Oligomerization of electron-deficient vinyl monomers through an ate-complex mechanism: a new role for b(c(6) f(5) )(3) lewis Acid. | LitMetric
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Oligomerization of electron-deficient vinyl monomers through an ate-complex mechanism: a new role for b(c(6) f(5) )(3) lewis Acid.

Emmanuel Pouget Erlea Holgado-Garcia Irina V Vasilenko Sergei V Kostjuk Jean Marc Campagne Francois Ganachaud

Macromol Rapid Commun

Institut Charles Gerhardt - UMR 5253 CNRS/UM2/ENSCM/UM1, Ecole Nationale Supérieure de Chimie de Montpellier, 8 rue de l'Ecole Normale, 34296 Montpellier Cedex 5, France.

Published: July 2009

AI Article Synopsis

  • The Lewis acid B(C(6)F(5))(3) paired with hydrosilanes effectively promotes the oligomerization of sulfone- and phosphonate-based monomers.
  • This reaction leads to the development of advanced silicone-based materials, like thermoplastic elastomers and heat-resistant polysiloxanes.
  • These new materials have potential applications in high-tech industries due to their desirable properties.

Article Abstract

The Lewis acid B(C(6) F(5) )(3) in combination with hydrosilanes exhibits remarkable activity in the oligomerization of sulfone- and phosphonate-based monomers. This process opens new routes to high-tech silicone-based materials, i.e., thermoplastic elastomers and heat-resistant polysiloxanes.

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 Source
http://dx.doi.org/10.1002/marc.200900173DOI Listing

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