AI Article Synopsis
- Ortho-(Dimesitylboryl)phenylphosphines 1 and 2 were used in palladium-catalyzed Suzuki-Miyaura carbon-carbon coupling reactions.
- The research involved coordination studies to understand how the structure of these compounds affects their reactivity in these reactions.
- A new coordination mode was discovered for phosphine-arylboranes, which includes a unique secondary π-interaction between a mesityl group on boron and the palladium metal center.
Article Abstract
ortho-(Dimesitylboryl)phenylphosphines 1 and 2 were applied in Pd-catalyzed Suzuki-Miyaura C-C couplings. Coordination studies were performed in order to rationalize the relationship between structure and reactivity. Full characterization of a Pd(0) complex derived from 1 has evidenced a new coordination mode for phosphine-arylboranes involving secondary π-interaction between one of the mesityl groups at boron and the metal centre.
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| http://dx.doi.org/10.1039/c1cc12611c | DOI Listing |
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