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Multiple photosynthetic reaction centres composed of supramolecular assemblies of zinc porphyrin dendrimers with a fullerene acceptor. | LitMetric
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Multiple photosynthetic reaction centres composed of supramolecular assemblies of zinc porphyrin dendrimers with a fullerene acceptor.

Shunichi Fukuzumi Kenji Saito Kei Ohkubo Tony Khoury Yukiyasu Kashiwagi Mark A Absalom Suresh Gadde Francis D'Souza Yasuyuki Araki Osamu Ito Maxwell J Crossley

Chem Commun (Camb)

Department of Material and Life Science, Graduate School of Engineering, Osaka University, ALCA, Japan Science and Technology Agency, 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan.

Published: July 2011

Multiple photosynthetic reaction centres have successfully been constructed using supramolecular complexes of zinc porphyrin dendrimers [D(ZnP)(n): n = 4, 8, 16] with fulleropyrrolidine bearing a pyridine ligand (C(60)py). Efficient energy migration occurs completely between the ZnP units of dendrimers prior to the electron transfer with increasing the generation of dendrimers to attain an extremely long charge-separation lifetime.

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 Source
http://dx.doi.org/10.1039/c1cc11725dDOI Listing

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