Synthesis of erbium oxide nanosheets and up-conversion properties.

A novel erbium-based compound as well as Er(2)O(3) nanosheets have been synthesized through a simple hydrothermal route. The nanosheets are of 200 nm width and 10-15 nm thickness. It is suggested that this erbium-based compound has a possible formula of Er(2)O(5)H(4) with a primitive tetragonal structure (cell parameters: a = 8.465(1) and c = 15.117(2) Å). Face-centered cubic and body-centered cubic structured Er(2)O(3) nanosheets were obtained after calcination of this compound at 623 and 973 K, respectively, both having a paramagnetic behavior. Er(2)O(5)H(4) and Er(2)O(3) nanosheets have similar up-conversion properties with strong blue emission, which is rarely reported in the literature. The existence of absorbed surface contaminations in nanosheets might be the origin for the blue emission enhancement.