Many Ru and Os systems display photoactive (3)MLCT states. Systems activated by therapeutic window light in the absence of O(2) remain elusive. [(bpy)(2)Os(dpp)RhCl(2)(phen)](3+) photobinds and photocleaves DNA under red light in an oxygen independent manner, due to molecular design involving one Os chromophore coupled to a photoactive cis-Rh(III)Cl(2) moiety.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c1cc11562f | DOI Listing |
Publication Analysis
Top Keywords
osrh bimetallic
4
bimetallic independent
4
independent dna
4
dna cleavage
4
cleavage dna
4
dna photobinding
4
photobinding red
4
red therapeutic
4
therapeutic light
4
light excitation
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!