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The pentamethylcyclopentadienylsilicon(II) cation: synthesis, characterization, and reactivity.
Chemistry
July 2014
Faculty of Chemistry, University of Bielefeld, 33615 Bielefeld (Germany).
In the flourishing chemistry of divalent silicon, π-complex formation between silicon and the pentamethylcyclopentadienyl (Cp*) group is one of the successful strategies for thermodynamic and/or kinetic stabilization. Here, the diverse reactivity of the [Cp*Si](+) ion is described. Its chemistry is characterized by the addition of anionic and neutral nucleophiles and by the easy hapticity change and the leaving-group character of the Cp* group.
View Article and Find Full Text PDFThe pentamethylcyclopentadienylsilicon(II) cation as a catalyst for the specific degradation of oligo(ethyleneglycol) diethers.
Angew Chem Int Ed Engl
July 2011
Faculty of Chemistry, University of Bielefeld, Universitätstrasse 25, 33615 Bielefeld, Germany.
Novel pi-complexes of divalent silicon: mixed substituted neutral sandwich compounds and the half-sandwich cation (iPr5C5)Si+.
Chem Commun (Camb)
September 2006
Department of Chemistry, University of Bielefeld, Universitätsstrasse 25, D-33615 Bielefeld, Germany.
The pentamethylcyclopentadienylsilicon(II) cation, Me5C5Si+, opens up access to novel silicocene derivatives; the penta-iso-propylcyclopentadienylsilicon(II) cation, iPr5C5Si+, is obtained by reaction of the mixed silicocene (iPr5C5)(Me5C5)Si with H(OEt2)2+ Al[OC(CF3)3]4-.
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