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Ru-OH-Zr Site over Metal-Organic Frameworks Boosts Coreactant Activation for Efficient Electrochemiluminescence.
Nano Lett
December 2024
State Key Laboratory of Green Pesticide, International Joint Research Center for Intelligent Biosensing Technology and Health, College of Chemistry, Central China Normal University, Wuhan 430079, P.R. China.
Metal-organic frameworks (MOFs) are promising electrochemiluminescent (ECL) nanoemitters. Great endeavors have been made to optimize the inherent luminescent properties, yet most MOFs suffer from poor coreactant activation ability, resulting in limited ECL. Therefore, it is urgent to integrate and design efficient catalytic centers within MOFs.
View Article and Find Full Text PDFSynthesis, crystal structure and Hirshfeld surface analysis of (2-amino-1-methyl-benzimidazole-κ )aqua-bis-(4-oxopent-2-en-2-olato-κ ,')nickel(II) ethanol monosolvate.
Acta Crystallogr E Crystallogr Commun
October 2024
The mol-ecule of the title compound, [Ni(CHO)(CHN)(HO)]·CHOH, has triclinic () symmetry. This compound is of inter-est for its anti-microbial properties. The asymmetric unit comprises two independent complex mol-ecules, which are linked by N-H⋯O and O-H⋯O hydrogen bonds along [111].
View Article and Find Full Text PDFCrystal structure and Hirshfeld surface analysis of (nitrato-κ ,')(1,4,7,10-tetra-aza-cyclo-dodecane-κ )nickel(II) nitrate.
Acta Crystallogr E Crystallogr Commun
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Rigaku Americas Corporation, The Woodlands Texas 77381 USA.
The crystal structure of the title compound, [Ni(CHN)(NO)]NO, at room temperature, has monoclinic (2/) symmetry. The structure displays inter-molecular hydrogen bonding. The nickel displays a distorted bipyramidal geometry with the symmetric bidentate bonded nitrate occupying an equatorial site.
View Article and Find Full Text PDFRevealing the key role of interfacial oxygen activation over CoMnO@MnO in the catalytic oxidation of acetone.
J Hazard Mater
December 2024
Tianjin Key Lab of Indoor Air Environmental Quality Control, School of Environmental Science and Technology, Tianjin University, Tianjin 300350, China; State Key Laboratory of Engines, Tianjin University, Tianjin 300350, China. Electronic address:
The accumulation of intermediate products on the catalyst surface caused by insufficient oxygen activity is an important reason for the poor activity of catalysts towards oxygenated volatile organic compounds (OVOCs). CoMnO@MnO heterogeneous catalysts were fabricated to decipher the interfacial oxygen activation mechanism for efficient acetone oxidation. Experimental and theoretical explorations revealed that oxygen vacancies were easily formed at the interface.
View Article and Find Full Text PDFA novel efficient liquefaction process for corn starch through ternary deep eutectic solvent: Products characterization and liquefaction mechanism.
Int J Biol Macromol
December 2024
College of Biomass Science and Engineering, Sichuan University, Chengdu 610065, China; Key Laboratory of Leather Chemistry and Engineering of Ministry of Education, Sichuan University, Chengdu 610065, China. Electronic address:
A novel approach for the solvothermal liquefaction of corn starch (CS) was investigated, using ternary deep eutectic solvent (TDES) as both an acidic catalyst and a source of liquefaction reagent. Synergistic effects from multi-component TDES were observed, leading to milder reaction conditions (110 °C, 35 min) and improved product selectivity (relative content of polyhydroxy compounds up to 97.83 %).
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