The influence of volume fractions on the phase behaviors of linear A(BC)(n)BA' multiblock terpolymers.

Phys Chem Chem Phys

The Key Laboratory of Molecular Engineering of Polymers, Ministry of Education, China.

Published: July 2011

The phase behaviors of A(BC)(n)BA' linear multiblock terpolymers are investigated using the pseudo-spectral method of self-consistent field theory by varying the volume fractions of different blocks. The relative stability among the lamellae-in-lamellae structures with different BC internal layers is tuned by the volume fraction of the two long tails. A larger A volume fraction favors the formation of structures with fewer BC thin layers. When the volume fraction of A is increased further, a hierarchical cylinder phase can be formed because of the effect of the spontaneous curvature and vice versa. The separation between B and C significantly reduces the phase regime of the cylinder, especially for the case of small A volume fraction.

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http://dx.doi.org/10.1039/c1cp20633hDOI Listing

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