μ-XAFS analysis using an X-ray μ-beam (1000 nm (h) × 800 nm (v)) was successfully carried out on a single particle of a practical catalyst NiO(x)/Ce(2)Zr(2)O(y) (0 ≤x≤ 1, 7 ≤y≤ 8). The oxidation state and local coordination structure of the NiO(x)/Ce(2)Zr(2)O(y) particle were characterized by Ni K-edge μ-XANES and μ-EXAFS, which showed the catalytically active and inactive phases of a single catalyst particle.
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http://dx.doi.org/10.1039/c1cp20895k | DOI Listing |
ACS Nano
January 2025
Jiangsu Key Laboratory of Frontier Material Physics and Devices, School of Physical Science and Technology, Soochow University, Suzhou, Jiangsu 215006, China.
Circular differential scattering (CDS) spectroscopy has been developed as a powerful method for the characterization of the optical activity of individual plasmonic nanostructures and their complexes with chiral molecules. However, standard measurement setups often result in artifacts that have long raised concerns on the interpretation of spectral data. In fact, the detection limit of CDS setups is constrained by the high level of artifacts, to ±10%.
View Article and Find Full Text PDFSoft Matter
January 2025
Van 't Hoff Laboratory of Physical and Colloid Chemistry, Department of Chemistry, Debye Institute for Nanomaterials Science, Utrecht University, Utrecht, The Netherlands.
Bicontinuous particle-stabilized emulsions (bijels) are unique soft materials that combine the bulk properties of two immiscible fluids into a single interconnected structure. This structure is achieved through the formation of two interwoven fluid networks, stabilized by an interfacial layer of colloidal particles. Bijels with submicron-scale domain networks can be synthesized solvent transfer-induced phase separation (STrIPS).
View Article and Find Full Text PDFJ Acoust Soc Am
January 2025
Center for Acoustics Research and Education, University of New Hampshire, Durham, New Hampshire 03823, USA.
Fishes and aquatic invertebrates utilize acoustic particle motion for hearing, and some additionally detect sound pressure. Yet, few underwater soundscapes studies report particle motion, which is often assumed to scale predictably with pressure in offshore habitats. This relationship does not always exist for low frequencies or near reflective boundaries.
View Article and Find Full Text PDFAnal Chem
January 2025
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830, United States.
A novel employment of single particle-inductively coupled plasma-mass spectrometry (SP-ICP-MS) was developed, where a microextraction (ME) probe is used to sample nanoparticles from a surface and analyze them in a single analytical step. The effects of several parameters on the performance of ME-SP-ICP-MS were investigated, including the flow rate, choice of carrier solution, particle size, and the design of the microextraction probe head itself. The optimized ME-SP-ICP-MS technique was used to compare the extraction efficiency (EE, defined as the ratio of particles measured to particles deposited on the surface) of the commercial probe head to a newly designed SP polyether ether ketone (PEEK) probe head.
View Article and Find Full Text PDFJ Virol
January 2025
Infection Biology Unit, German Primate Centre - Leibniz Institute for Primate Research, Göttingen, Germany.
The naturally occurring mutation E484D in the spike (S) protein of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) can render viral entry ACE2 independent and imdevimab resistant. Here, we investigated whether the cellular proteins ASGR1, DC-SIGN, and TMEM106B, which interact with the viral S protein, can contribute to these processes. Employing S protein-pseudotyped particles, we found that expression of ASGR1 or DC-SIGN jointly with TMEM106B allowed for robust entry of mutant E484D into otherwise non-susceptible cells, while this effect was not observed upon separate expression of the single proteins and upon infection with SARS-CoV-2 wild type (WT).
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