Vanadate (Na3VO4) action of the isometric force of maximal Ca2(+)-activated fibre has been studied at pH from 6.3 to 7.3. Acidification was shown to decrease the force declining vanadate effect: appearance of the dissociation constant estimated from force--H2VO4--dependence increases about two-fold following the pH decreasing from 7.3 to 6.3. Therefore the well-known decline of the force at acidification is accompanied by a decrease of the sensitivity to vanadate. These both phenomena can have a common nature and reflect, for example, a decreasing complex AM.ADP+ responsible for the force and interaction with vanadate. Our findings permit to think that the changes in pH with fatigue increasing the diprotonated form of phosphate simultaneously reduce the sensitivity of the contractile system to this form.
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Spectrochim Acta A Mol Biomol Spectrosc
January 2025
College of Chemical and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022 China.
In recent years, it has become a development trend to design multi-application luminescent materials with rare earth ion doping. In this work, a series of Eu/Sm doped self-activated NaYMgVO (NYMVO) phosphors were synthesized through a simple high-temperature solid-state reaction method. Interestingly, due to the energy transfer (ET) from the matrix to the activators, the luminescence color of the phosphors changed from turquoise to orange-red and yellow-green under near-ultraviolet (n-UV) 365 nm excitation.
View Article and Find Full Text PDFPLoS One
January 2025
School of Earth and Environmental Sciences, Seoul National University, Seoul, South Korea.
The oxidation states of vanadium determine its mobility and toxicity, and dissimilatory vanadate reduction has been reported in several microorganisms, highlighting the potential significance of this pathway in the remediation of vanadium contamination and the biogeochemical cycle. However, to date, most known microorganisms capable of reducing vanadate are Gram-negative respiratory bacteria belonging to the phylum Proteobacteria. In this study, we isolated Tepidibacter mesophilus strain VROV1 from deep-sea sediments on the northern Central Indian Ridge and investigated its ability to reduce vanadium and the impact of vanadate on its cellular metabolism.
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January 2025
Molecular Diagnostic Center, Key Laboratory of Clinical Cancer Pharmacology and Toxicology Research of Zhejiang Province, Hangzhou First People's Hospital, Hangzhou 310006, China.
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View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Institute of Electrochemistry, Ulm University, Albert-Einstein-Allee 47, Ulm 89081, Germany.
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View Article and Find Full Text PDFRSC Adv
January 2025
School of Electronic Engineering, Guangxi Key Laboratory of Multidimensional Information Fusion for Intelligent Vehicles, Guangxi University of Science and Technology Liuzhou 545000 China
This study presents a novel approach to enhance photoelectrochemical (PEC) water oxidation by integrating cobalt phthalocyanine (CoPc) with bismuth vanadate (BVO) a direct solvothermal method. The as-prepared BVO@CoPc photoanode demonstrated a photocurrent density of 4.0 mA cm at 1.
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