The rate constants for the reactions of OH radicals with fully fluorinated alkenes containing different numbers of -CF(3) groups next to olefinic carbon, CF(2)═CF(2), CF(2)═CFCF(3), CF(3)CF═CFCF(3), and (CF(3))(2)C═CFC(2)F(5), were measured between 230 and 480 K using the flash photolysis resonance fluorescence technique to give the following expressions: k(C(2)F(4))(250-480 K) = 1.32 × 10(-12) × (T/298 K)(0.9) × exp(+600 K/T) cm(3) molecule(-1) s(-1), k(C(3)F(6))(230-480 K) = 9.75 ×10(-14) × (T/298 K)(1.94) × exp(+922 K/T) cm(3) molecule(-1) s(-1), k(trans-C(4)F(8))(230-370 K) = 7.50 × 10(-14) × (T/298 K)(1.68) × exp(+612 K/T) cm(3) molecule(-1) s(-1), k(cis-C(4)F(8))(230-370 K) = 2.99 × 10(-14) × (T/298 K)(2.61) × exp(+760 K/T) cm(3) molecule(-1) s(-1), and k(C(6)F(12))(250-480 K) = 2.17 × 10(-15) × (T/298 K)(3.90) × exp(+1044 K/T) cm(3) molecule(-1) s(-1). The kinetics of the OH reaction in an industrial sample of octofluoro-2-propene (a mixture of the cis- and trans-isomers of CF(3)CF═CFCF(3)) was studied to determine the "effective" reaction rate constant for the typically industrial mixture: k(
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