Lewis acid-activated oxidation of alcohols by permanganate. | LitMetric

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Lewis acid-activated oxidation of alcohols by permanganate. | LitMetric

Lewis acid-activated oxidation of alcohols by permanganate.

Hongxia Du Po-Kam Lo Zongmin Hu Haojun Liang Kai-Chung Lau Yi-Ning Wang William W Y Lam Tai-Chu Lau

Chem Commun (Camb)

CAS Key Laboratory of Soft Matter Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, PR China.

Published: July 2011

The oxidation of alcohols by KMnO(4) is greatly accelerated by various Lewis acids. Notably the rate is increased by 4 orders of magnitude in the presence of Ca(2+). The mechanisms of the oxidation of CH(3)OH and PhCH(OH)CH(3) by MnO(4)(-) and BF(3)·MnO(4)(-) have also been studied computationally by the DFT method.

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http://dx.doi.org/10.1039/c1cc12024g	DOI Listing

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