4-Amino-pyridinium azide 4-amino-pyridine solvate.

Acta Crystallogr Sect E Struct Rep Online

Published: November 2010

AI Article Synopsis

  • - The compound is made up of a 4-amino-pyridinium cation and a 4-amino-pyridine molecule, along with an azide anion, where the nitrogen atoms in the azide are symmetrically arranged.
  • - The 4-amino-pyridinium cation and 4-amino-pyridine molecule essentially behave as identical due to their symmetry and occupy the same position in the crystal structure.
  • - A network of hydrogen bonds (N-H⋯N) between molecules contributes to a stable three-dimensional structure, which helps in organizing the crystal's overall packing.

Article Abstract

In the title compound, C(5)H(7)N(2) (+)·N(3) (-)·C(5)H(6)N(2), all N atoms of the azide anion are situated on a twofold rotational axis, so the 4-amino-pyridinium cation and 4-amino-pyridine mol-ecule, being related by symmetry, occupy one position in the asymmetric unit. Inter-molecular N-H⋯N hydrogen bonds generate a three-dimensional hydrogen-bonding network which consolidates the crystal packing.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011494PMC
http://dx.doi.org/10.1107/S1600536810044843DOI Listing

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