In the title coordination polymer, {[Eu(C(7)H(2)NO(5))(H(2)O)(3)]·H(2)O}(n), the Eu(III) atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxyl-ate (hpc) trianion, two monodentate hpc anions and three water mol-ecules, forming a distorted bicapped trigonal-prismatic coordination geometry. The hpc ligands bridge adjacent Eu(III) ions, forming infinite double chains. Adjacent chains are further connected by hpc ligands into sheets. O-H⋯O hydrogen bonds then generate a three-dimensional supra-molecular framework.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011704 | PMC |
http://dx.doi.org/10.1107/S1600536810048518 | DOI Listing |
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!