(2,2'-Biquinoline-κN,N')dibromido-zinc(II).

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, University of Sistan and Baluchestan, PO Box 98135-674, Zahedan, Iran.

Published: November 2010

In the title compound, [ZnBr(2)(C(18)H(12)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the 2,2'-biquinoline ligand and two terminal Br atoms. The crystal packing is stabilized by weak inter-molecular C-H⋯Br hydrogen bonds and extensive inter-molecular π-π contacts between the pyridine and benzene rings [centroid-centroid distances = 3.775 (4), 3.748 (4), 3.735 (4), 3.538 (4), 3.678 (4) and 3.513 (4) Å].

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011677PMC
http://dx.doi.org/10.1107/S1600536810047434DOI Listing

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