In the title complex, [Co(C(6)H(14)NO(3))(N(3))] or [Co(teaH(2))N(3)], the Co(II) atom resides in a trigonal-bipymidal O(3)N(2) environment formed by three O atoms and one N atom from a simply deprotonated tetra-dentate triethano-lamine ligand, and one N atom from an azide ligand. The O atoms define the equatorial plane whereas both N atoms are in axial positions. The mononuclear units are linked through O-H⋯O hydrogen-bonding inter-actions between the ethanol OH groups and the ethano-late O atom of a neighbouring complex into chains running parallel to [010].
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| http://dx.doi.org/10.1107/S1600536810047100 | DOI Listing |
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Azido-{2-[bis-(2-hy-droxy-eth-yl)amino]-ethano-lato-κN,O,O',O''}cobalt(II).
Acta Crystallogr Sect E Struct Rep Online
November 2010
Pharmacy College, Henan University of Traditional Chinese Medicine, Zhengzhou 450008, People's Republic of China.
In the title complex, [Co(C(6)H(14)NO(3))(N(3))] or [Co(teaH(2))N(3)], the Co(II) atom resides in a trigonal-bipymidal O(3)N(2) environment formed by three O atoms and one N atom from a simply deprotonated tetra-dentate triethano-lamine ligand, and one N atom from an azide ligand. The O atoms define the equatorial plane whereas both N atoms are in axial positions. The mononuclear units are linked through O-H⋯O hydrogen-bonding inter-actions between the ethanol OH groups and the ethano-late O atom of a neighbouring complex into chains running parallel to [010].
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