1-Methane-sulfonyl-1H-1,2,3-benzotriazole.

Acta Crystallogr Sect E Struct Rep Online

Department of Inorganic Chemistry, Faculty of Science, Charles University in Prague; Hlavova 2030, 12840 Prague 2, Czech Republic.

Published: October 2010

The mol-ecular geometry of the title compound, C(7)H(7)N(3)O(2)S, does not differ much from that of the previously reported 4-toluene-sulfonyl analogue. Unlike the latter compound, however, mol-ecules of the title compound associate primarily via π-π stacking inter-actions of their benzene rings [centroid-centroid distance = 3.5865 (8) Å], forming columnar stacks along the crystallographic 2(1) axes. These stacks are inter-connected via weak C-H⋯O and C-H⋯N hydrogen bonds.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009158PMC
http://dx.doi.org/10.1107/S1600536810040778DOI Listing

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