The title compound, C(14)H(11)BrN(4)O(4), contains 3-bromo-phenyl and 2,4-dinitro-phenyl groups on opposite sides of a hydrazone unit and crystallizes with two mol-ecules in the asymmetric unit. The dihedral angles between the two ring systems in each mol-ecule are 2.0 (1) and 2.5 (4)°. Weak C-H⋯O hydrogen bonds and weak π-π stacking inter-actions [centroid-centroid distance = 3.7269 (14) Å] help to establish the packing. Intra-molecular N-H⋯O hydrogen bonds are also observed. On one of the rings, the Br atom is disordered over two equivalent positions of the phenyl ring [occupancy ratio 0.8734 (10):0.1266 (10).

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008979PMC
http://dx.doi.org/10.1107/S1600536810037980DOI Listing

Publication Analysis

Top Keywords

hydrogen bonds
8
1e-1-3-bromo-phen-ylethanone 24-di-nitro-phenyl-hydrazone
4
24-di-nitro-phenyl-hydrazone title
4
title compound
4
compound c14h11brn4o4
4
c14h11brn4o4 3-bromo-phenyl
4
3-bromo-phenyl 24-dinitro-phenyl
4
24-dinitro-phenyl groups
4
groups opposite
4
opposite sides
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!