Aqua-(hippurato)bis-(1,10-phenanthroline)cobalt(II) nitrate monohydrate.

Acta Crystallogr Sect E Struct Rep Online

Published: October 2010

In the title compound, [Co(C(9)H(8)NO(3))(C(12)H(8)N(2))(2)(H(2)O)]NO(3)·H(2)O, the Co(II) atom is six-coordinated by a carboxylate O atom of the hippurate (Hc) anion, a water O atom and four N atoms from two 1,10-phenanthroline ligands in a distorted octa-hedral geometry. The uncoordinated O atom of the hippuric acid anion is involved in an intra-molecular hydrogen bond to the coordinated water mol-ecule. The crystal packing is stabilized by inter-molecular O-H⋯O hydrogen bonds involving the Hc anions, the coordinated water mol-ecule, the nitrate anion and the uncoordinated water mol-ecule.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009208PMC
http://dx.doi.org/10.1107/S1600536810040602DOI Listing

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