In the title complex, [Cd(C(14)H(9)N(5))(NO(3))(H(2)O)(2)]NO(3), the Cd(II) ion is coordinated in a distorted penta-gonal-bipyramidal geometry. The equatorial sites are occupied by a 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligand in a tridentate coordination mode and a bis-chelating nitrate ligand. Two aqua ligands are coordinated at the axial sites. All non-H atoms in the equatorial plane are co-planar within 0.0673 Å. In the crystal, inter-molecular O-H⋯O and O-H⋯N hydrogen bonds connect the components into a two-dimensional network parallel to (001). In addition, there is a π-π stacking inter-action between symmetry-related benzene rings, with a centroid-centroid distance of 3.598 (3) Å.
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http://dx.doi.org/10.1107/S1600536810039735 | DOI Listing |
Bioresour Technol
June 2024
School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, China. Electronic address:
Denitrification is fragile to toxic substances, while currently there are few regulation strategies for toxic substance-stressed denitrification. This study proposed a combined bio-promoter composed of basic bio-promoter (cytokinin, biotin, L-cysteine, and flavin adenine dinucleotide) and phosphomolybdic acid (PMo) to recover cadmium(II) (Cd(II)) stressed denitrification. By inhibiting 58.
View Article and Find Full Text PDFJ Colloid Interface Sci
May 2024
Center for Advanced Materials Research, Henan Key Laboratory of Functional Salt Materials, Zhongyuan University of Technology, Zhengzhou, Henan 450007, PR China. Electronic address:
Optimizing friction materials based on molecular diversity in a molecular framework system is an effective method to improve the output performance of triboelectric nanogenerators (TENGs). In this study, three cadmium(II) metal-organic frameworks (Cd-MOFs) with different cavities were synthesized solvothermally by the assembly of cadmium nitrate (Cd(NO)·4HO), 4',4'''-carbonylbis(([1,1'-biphenyl]-3,5-dicarboxylic acid)) (HCBBD), and trans-1,2-bis(4-pyridyl)ethylene (4,4'-bpe) via a solvent-regulated strategy. The topology and porosity of Cd-MOFs could be controlled effectively by the solvent constituents and were demonstrated to be closely related to their triboelectric behaviors.
View Article and Find Full Text PDFHeliyon
June 2022
Department of Chemistry, Faculty of Science, University of Chittagong, Chattogram, 4331, Bangladesh.
The isomeric ligand L, a saturated analogue of 2,9-C-meso-Me[14]diene, on reflux with excess acrylonitrile afforded 1,8-N-pendant cyanoethyl derivative L. Interaction of L with cadmium(II) perchlorate, nitrate, acetate, and chloride salts produced six coordinated octahedral compounds, [Cd(L) (ClO)]∙2HO, [Cd(L) (NO)], [Cd(L) (CHCOO)], and [Cd(L)Cl], respectively. Further, axial substitution reactions between [Cd(L) (ClO)]∙2HO and KI, KBr, KCl, KSCN, and NaNO in a 1:2 ratio yielded six coordinated octahedral compounds, [Cd(L)I]∙HO, [Cd(L)Br]∙2HO, [Cd(L)Cl(ClO)]∙2HO, [Cd(L) (NCS)]∙HO, and [Cd(L) (NO) (ClO)]∙2HO, respectively.
View Article and Find Full Text PDFMolecules
September 2021
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Lavrentiev Ave., 630090 Novosibirsk, Russia.
Coordination polymers with a new rigid ligand 1,3-bis(1,2,4-triazol-1-yl)adamantane (L) were prepared by its reaction with cadmium(II) or silver(I) nitrates. Crystal structure of the coordination polymers was determined using single-crystal X-ray diffraction analysis. Silver formed two-dimensional coordination polymer [Ag(L)NO], in which metal ions are linked by 1,3-bis(1,2,4-triazol-1-yl)adamantane ligands, coordinated by nitrogen atoms at positions 2 and 4 of 1,2,4-triazole rings.
View Article and Find Full Text PDFJ Inorg Biochem
June 2021
Laboratory of Inorganic Chemistry, Faculty of Chemistry, Aristotle University of Thessaloniki, GR-54124 Thessaloniki, Greece. Electronic address:
The interaction of the recently reported quinazoline derivative (E)-4-(2-(pyridin-2-ylmethylene)hydrazinyl)quinazoline (L) with a series of metal(II) (= copper(II), nickel(II), cobalt(II) and cadmium(II)) chlorides or nitrates resulted in the formation of mononuclear complexes which were characterized by spectroscopic techniques and single-crystal X-ray crystallography, i.e. [Cu(L)]Cl·4HO (1·4HO), [Ni(L)]Cl·4HO (2·4HO), [Ni(L)](NO)·MeOH (3·MeOH), [Co(L)]Cl·4HO (4·4HO), [Co(L)](NO)·HO (5·HO), [Co(L)](NO)·2.
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