Tribenzylbis(triphenyl-arsine oxide-κO)tin(IV) tetra-phenyl-borate.

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

Published: October 2010

The crystal structure of the title salt, [Sn(C(7)H(7))(3)(C(18)H(15)AsO)(2)][B(C(6)H(5))(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry [summation of C-Sn-C angles 360.0 (3)° and O-Sn-O angle 173.1 (1)°]. The structure contains voids of 113 (19) Å(3), but no solvent mol-ecule could reasonably be located there.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009232PMC
http://dx.doi.org/10.1107/S1600536810039450DOI Listing

Publication Analysis

Top Keywords

tribenzylbistriphenyl-arsine oxide-κotiniv
4
oxide-κotiniv tetra-phenyl-borate
4
tetra-phenyl-borate crystal
4
crystal structure
4
structure title
4
title salt
4
salt [snc7h73c18h15aso2][bc6h54]
4
[snc7h73c18h15aso2][bc6h54] consists
4
consists discrete
4
discrete cations
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!