In the title complex, [PdBr(C(4)H(3)N(2))(C(18)H(15)P)(2)], the geometry around the Pd(II) atom is distorted square-planar with the Pd(II) atom displaced by 0.0150 (5) Å from the least-squares BrP(2)C plane. Two PPh(3) ligands are in trans positions [P-Pd-P = 176.743 (17)°], while the pyrimidinyl ligand and Br atom are trans to one another [C-Pd-Br = 176.56 (5)°]. Structural parameters from NMR, IR and mass spectra are in agreement with the crystal structure of the title compound.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009198 | PMC |
| http://dx.doi.org/10.1107/S1600536810038511 | DOI Listing |
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