In the title thio-cyanate-bridged polynuclear copper(II) complex, [Cu(C(10)H(12)NO(3))(NCS)](n), the Cu atom is five-coordinated in a square-pyramidal geometry, with one phenolato O, one imino N and one hy-droxy O atom of a Schiff base ligand and one thio-cyanato N atom defining the basal plane, and with one thio-cyanato S atom occupying the apical position. In the crystal structure, pairs of adjacent complex mol-ecules are linked through inter-molecular O-H⋯O hydrogen bonds into dimers. The dimers are further linked via Cu⋯S inter-actions, forming two-dimensional layers parallel to the bc plane.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008078 | PMC |
| http://dx.doi.org/10.1107/S1600536810034021 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
-Poly[[di-phenyl-tin(IV)]-di-μ-iso-thio-cyanato]: an unprecedented layered coordination polymer resulting from bridging κ : thio-cyanato ligands.
IUCrdata
November 2024
Chemistry, Osnabrück University, Barabarstr. 7, 49069 Osnabrück, Germany.
In the title compound, di-phenyl-tin(IV) diiso-thio-cyanate, [Sn(NCS)(CH)] or PhSn(NCS), comparatively long tin-nitro-gen and short tin-sulfur bonds prove that the ambidentate iso-thio-cyanate ion acts as a bridge between two neighboring, octa-hedrally coordinated tin atoms. As a result, the mol-ecules lose their individuality in favor of a layered coordination polymer that represents a new type of mol-ecular inter-actions in the structural chemistry of diorganotin(IV) dihalides/pseudohalides. The tin atom is located on a center of inversion.
View Article and Find Full Text PDFSynthesis, crystal structure and properties of chlorido-tetra-kis-(pyridine-3-carbo-nitrile)-thio-cyanato-iron(II).
Acta Crystallogr E Crystallogr Commun
December 2023
Institut für Anorganische Chemie, Universität Kiel, Max-Eyth. Str. 2, 24118 Kiel, Germany.
Reaction of FeCl·4HO with KSCN and 3-cyano-pyridine (pyridine-3-carbo-nitrile) in ethanol accidentally leads to the formation of single crystals of Fe(NCS)(Cl)(3-cyano-pyridine) or [FeCl(NCS)(CHN)]. The asymmetric unit of this compound consists of one Fe cation, one chloride and one thio-cyanate anion that are located on a fourfold rotation axis as well as of one 3-cyano-pyridine coligand in a general position. The Fe cations are sixfold coordinated by one chloride anion and one terminally N-bonding thio-cyanate anion in -positions and four 3-cyano-pyridine coligands that coordinate the pyridine N atom to the Fe cations.
View Article and Find Full Text PDFTetra-kis(tri-ethyl-enediamin-1-ium) dodeca-μ-chlorido-hexakis(thio-cyanato-κ)hexa--niobate.
IUCrdata
May 2023
Universität Rostock, Institut für Chemie, Anorganische Festkörperchemie, Albert-Einstein-Str. 3a, D-18059 Rostock, Germany.
The crystal structure of the cluster complex salt, (CHN)[Nb(NCS)Cl] or (H-DABCO)[NbCl(NCS)] (DABCO = tri-ethyl-enedi-amine or 1,4-di-aza-bicyclo-[2.2.2]octa-ne), comprises octa-hedral Nb cluster cores, which are μ-coordinated by 12 chloride ligands (bridging the octa-hedral edges, ligand sphere).
View Article and Find Full Text PDFIsolation and structural comparison of Ru-dnp complexes [dnp = 2,6-bis-(1,8-naphthyridin-2-yl)pyridine] with axially or equatorially coordinating NCS ligands.
Acta Crystallogr E Crystallogr Commun
June 2022
Department of Natural Sciences and Informatics, Fukushima University, 1, Kanayagawa, Fukushima 960-1296, Japan.
Article Synopsis
- - Two ruthenium(II) complexes, referred to as complexes I and II, are characterized by their molecular and crystal structures, featuring a thio-cyanato group and a polypyridyl ligand for coordination.
- - Each complex has a ruthenium atom in a distorted octahedral geometry, with different ligand arrangements: axial coordination for complex I and equatorial coordination for complex II.
- - The crystal structures exhibit various hydrogen bonding interactions (intra- and inter-molecular), as well as π-π interactions, which play a role in the stability and properties of these complexes.
Synthesis, crystal structure and thermal properties of poly[bis-[μ-3-(amino-meth-yl)pyridine-κ :']bis(thio-cyanato-κ)manganese(II)].
Acta Crystallogr E Crystallogr Commun
August 2021
Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, Max-Eyth-Str. 2, D-24118 Kiel, Germany.
The reaction of Mn(NCS) with a stoichiometric amount of 3-(amino-meth-yl)pyridine in ethanol led to the formation of the title compound, [Mn(NCS)(CHN)] , which is isotypic to its Zn, Co and Cd analogues. The manganese cation is located on a centre of inversion and is octa-hedrally coordinated in an all- configuration by two terminal N-bonded thio-cyanate anions as well as four 3-(amino-meth-yl)pyridine co-ligands, of which two coordinate with the pyridine N atom and two with the amino N atom. The 3-(amino-meth-yl)pyridine co-ligands connect the Mn cations into layers extending parallel to (10).
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!