Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN)cobalt(II).

Acta Crystallogr Sect E Struct Rep Online

Published: August 2010

In the title compound, [Co(II)Cl(2)(C(6)H(10)N(2))(2)], a pair of 3,4,5-trimethyl-pyrazoles act as monodentate ligands. Two Cl(-) anions are also bonded directly to the Co(II) atom, which has a CoN(2)Cl(2) chromophore in a slightly distorted tetra-hedral geometry. The two mol-ecules in the asymmetric unit are related by an approximate twofold rotation roughly parallel to the a axis. The amino H atom in the pyrazole ring participates in weak N-H⋯Cl hydrogen bonds to form chains that propagate roughly parallel to the c axis.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007936PMC
http://dx.doi.org/10.1107/S160053681003254XDOI Listing

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