AI Article Synopsis
- The organotin compound features a tin (Sn) atom that is bonded to various atoms including sulfur (S), oxygen (O), and nitrogen (N) from a tridentate ligand, as well as a chloride ligand, phenyl carbon, and a water molecule, creating a distorted octahedral shape.
- Coordinated water molecules facilitate connections between organotin molecules through O-H⋯O hydrogen bonds with carbonyl and carboxylate groups, forming 12-membered synthons.
- These synthons combine to create supramolecular chains that align along the c axis, with additional stacking in the ac plane and interlayer connections via N-H⋯Cl hydrogen bonds.
Article Abstract
In the title organotin compound, [Sn(C(6)H(5))(C(10)H(15)N(3)O(2)S)Cl(H(2)O)], the Sn atom is coordinated by the S, O, and imine N atoms of the dinegative tridentate ligand, a chloride ligand, the ipso-C atom of a phenyl ligand and by a water mol-ecule in a distorted octa-hedral coordination environment. Coordin-ated water mol-ecules link the organotin mol-ecules by forming O-H⋯O hydrogen bonds with both carbonyl and carboxyl-ate O atoms, leading to 12-membered {⋯OCO⋯HOH⋯}(2) synthons. This results in the formation of supra-molecular chains along the c axis. The chains pack in the ac plane and stack along the b axis with links between layers afforded by N-H⋯Cl hydrogen bonds.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007908 | PMC |
| http://dx.doi.org/10.1107/S1600536810031715 | DOI Listing |
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