Dichlorido[(S)-N-(1-phenyl-ethyl-idene)-1-(pyridin-2-yl)ethanamine-κN,N']zinc(II) dichloro-methane solvate.

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, Kyungpook National University, Taegu, 702-701, Republic of Korea.

Published: July 2010

In the title compound, [ZnCl(2)(C(15)H(16)N(2))]·CH(2)Cl(2), the Zn(II) atom has a distorted tetra-hedral coordination by two Cl atoms and two N atoms from the organic ligand [the average Zn-N and Zn-Cl bond lengths are 2.060 (4) Å and Zn-Cl = 2.179 (16) Å, respectively]. The dihedral angle between the N-Zn-N and Cl-Zn-Cl planes is 89.9 (1)°. The phenyl ring forms a dihedral angle of 40.6 (5)° with the imine plane.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007472PMC
http://dx.doi.org/10.1107/S1600536810029387DOI Listing

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