In the title compound, C(25)H(17)N(3)O(2)S, the coumarin ring system is essentially planar with a maximum deviation of 0.019 (2) Å. A weak intra-molecular C-H⋯O hydrogen bond stabilizes the mol-ecular structure, so that the coumarin plane is approximately coplanar with the thia-zole ring, making a dihedral angle of 2.5 (10)°. The two phenyl rings are nearly perpendicular to each other, with a dihedral angle of 81.44 (12)°. In the crystal structure, the mol-ecules are linked into an infinite chain along the b axis by inter-molecular C-H⋯O hydrogen bonds. Weak C-H⋯π inter-actions are observed between the chains.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007000PMC
http://dx.doi.org/10.1107/S1600536810023627DOI Listing

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