Triethyl-ammonium 1,1'-binaphthyl-2,2'-diyl phosphate.

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, IIT Madras, Chennai, TamilNadu, India.

Published: June 2010

In the crystal structure of the title compound, C(6)H(16)N(+)·C(20)H(12)O(4)P(-), an N-H⋯O inter-action links the cation to the anion. The N atom in the triethyl-ammonium cation exhibits a trigonal-bipyramidal coordination geometry and forms an N-H⋯O inter-action with one phosphate O atom of the 1,1'-binaphthyl-2,2'-diyl phosphate ligand. A bifurcated C-H⋯O inter-action with the other phosphate O atom links molecules along the a axis. The dihedral angle between the two naphthyl ring systems is 58.92 (3)°. The refined Flack parameter value of 0.50 (10) indicates inversion twinning.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006757PMC
http://dx.doi.org/10.1107/S160053681002026XDOI Listing

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