Tetra-carbonyl-1κC,3κC-bis[1,3(η)-cyclo-penta-dien-yl]dihydroxido-2κO-diirontin(2 Fe-Sn) monohydrate.

Acta Crystallogr Sect E Struct Rep Online

Institut für Chemie, Naturwissenschaftliche Fakulät II, Martin-Luther-Universität Halle-Wittenberg, Kurt-Mothes-Strasse 2, 06120 Halle, Germany.

Published: June 2010

In the title hydrate, [Fe(2)Sn(C(5)H(5))(2)(OH)(2)(CO)(4)]·H(2)O, the central Sn atom is tetra-hedrally coordinated by two {Cp(CO)(2)Fe} fragments and two hydroxide groups. The [{Cp(CO)(2)Fe}(2)Sn(OH)(2)] and water mol-ecules are linked by O-H⋯O hydrogen bridges, giving two-dimensional arrays with 4.8(2) topology that stack along the c axis.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006954PMC
http://dx.doi.org/10.1107/S1600536810021975DOI Listing

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