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[(Methyl-carbamothio-yl)disulfan-yl]methyl N-methyl-carbamodithio-ate. | LitMetric

The title compound, C(5)H(10)N(2)S(5), was unintentionally obtained as the product of an attempted synthesis of a methyl-carbamodithioic acid using methyl-amine and carbon disulfide. In the mol-ecule, two dithio-carbamate groups are bridged by a -CH(2)S- unit. The C-S-S-C torsion angle is -90.13 (11)°. The crystal structure is stabilized by N-H⋯S inter-actions between neighbouring mol-ecules. An intra-molecular N-H⋯S hydrogen bond also occurs.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983331PMC
http://dx.doi.org/10.1107/S160053681003833XDOI Listing

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