In the title compound, C(16)H(12)ClFN(2), the dihedral angle between the quinoline ring system and the flourophenyl ring is 86.70 (4)°. In the crystal, mol-ecules are linked into chains along the a axis by N-H⋯N hydrogen bonds. In addition, C-H⋯π inter-actions involving the two benzene rings are observed.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983417PMC
http://dx.doi.org/10.1107/S1600536810036056DOI Listing

Publication Analysis

Top Keywords

n-[2-chloro-3-quinol-ylmeth-yl]-4-fluoro-aniline title
4
title compound
4
compound c16h12clfn2
4
c16h12clfn2 dihedral
4
dihedral angle
4
angle quinoline
4
quinoline ring
4
ring system
4
system flourophenyl
4
flourophenyl ring
4

Similar Publications

Article Synopsis
  • - The compound CHFNO, a tetrahydropyridine, is synthesized through a one-pot reaction using 4-fluoro-aniline, ethyl acetoacetate, and benzaldehyde at room temperature, utilizing sodium lauryl sulfate as a catalyst.
  • - In its crystal form, CHFNO contains two molecules in the asymmetric unit and features a distorted boat conformation, with hydrogen bonding interactions contributing to its three-dimensional structure.
  • - Computational analysis using density functional theory (DFT) compares the optimized molecular structure with experimental data and examines the compound’s electronic properties through HOMO-LUMO behavior and Natural Bond Orbital (NBO) analysis.
View Article and Find Full Text PDF

In the title compound, [ZnCl(2)(C(6)H(6)FN)(2)], the Zn(II) atom has a slightly distorted tetra-hedral geometry, being coordinated by the N atoms of two 4-fluoro-aniline mol-ecules and the two Cl(-) anions. The two benzene rings are almost perpendicular to one another, making a dihedral angle of 89.96 (13)°.

View Article and Find Full Text PDF

4-Fluoro-anilinium tetra-chloridoferrate(III) 18-crown-6 clathrate.

Acta Crystallogr Sect E Struct Rep Online

June 2010

Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China.

The reaction of 4-fluoro-aniline hydro-chloride, 18-crown-6 and ferric chloride in methano-lic solution yields the title compound, (C(6)H(7)FN)[FeCl(4)]·C(12)H(24)O(6), which has an unusual supramolecular structure. N-H⋯O hydrogen-bonding inter-actions between the NH(3) (+) substituents of the 4-fluoro-anilinium cations and the O atoms of the crown ether mol-ecules result in a rotator-stator-like structure.

View Article and Find Full Text PDF

In the title compound, C(16)H(12)ClFN(2), the dihedral angle between the quinoline ring system and the flourophenyl ring is 86.70 (4)°. In the crystal, mol-ecules are linked into chains along the a axis by N-H⋯N hydrogen bonds.

View Article and Find Full Text PDF

N-(2-Fluoro-phen-yl)cinnamamide.

Acta Crystallogr Sect E Struct Rep Online

February 2010

The title compound, C(15)H(12)FNO, was prepared by the reaction of cinnamoyl chloride with 4-fluoro-aniline and crystallizes with two mol-ecules A and B in the asymmetric unit. The two unique mol-ecules are closely similar and overlay with an r.m.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!