In the title compound, C(16)H(12)ClFN(2), the dihedral angle between the quinoline ring system and the flourophenyl ring is 86.70 (4)°. In the crystal, mol-ecules are linked into chains along the a axis by N-H⋯N hydrogen bonds. In addition, C-H⋯π inter-actions involving the two benzene rings are observed.
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http://dx.doi.org/10.1107/S1600536810036056 | DOI Listing |
Acta Crystallogr E Crystallogr Commun
October 2023
School of Studies in Chemistry, Jiwaji University, Gwalior 474011, India.
In the title compound, [ZnCl(2)(C(6)H(6)FN)(2)], the Zn(II) atom has a slightly distorted tetra-hedral geometry, being coordinated by the N atoms of two 4-fluoro-aniline mol-ecules and the two Cl(-) anions. The two benzene rings are almost perpendicular to one another, making a dihedral angle of 89.96 (13)°.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
June 2010
Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China.
The reaction of 4-fluoro-aniline hydro-chloride, 18-crown-6 and ferric chloride in methano-lic solution yields the title compound, (C(6)H(7)FN)[FeCl(4)]·C(12)H(24)O(6), which has an unusual supramolecular structure. N-H⋯O hydrogen-bonding inter-actions between the NH(3) (+) substituents of the 4-fluoro-anilinium cations and the O atoms of the crown ether mol-ecules result in a rotator-stator-like structure.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
September 2010
In the title compound, C(16)H(12)ClFN(2), the dihedral angle between the quinoline ring system and the flourophenyl ring is 86.70 (4)°. In the crystal, mol-ecules are linked into chains along the a axis by N-H⋯N hydrogen bonds.
View Article and Find Full Text PDFThe title compound, C(15)H(12)FNO, was prepared by the reaction of cinnamoyl chloride with 4-fluoro-aniline and crystallizes with two mol-ecules A and B in the asymmetric unit. The two unique mol-ecules are closely similar and overlay with an r.m.
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