The Sn atom in the polymeric title compound, [Sn(C(6)H(5))(3)(C(10)H(16)NO(3))](n), is five-coordinated within a trans-C(3)O(2) donor set that defines an approximate trigonal-bipyramidal geometry. The carboxyl-ate ligand is monodentate and the amide O atom bridges a symmetry-related Sn atom, generating a chain along [010] with a linear topology. An intra-molecular carboxyl-ate-carbonyl N-H⋯O hydrogen bond is responsible for the curved conformation within the carboxyl-ate ligand.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983217PMC
http://dx.doi.org/10.1107/S1600536810036500DOI Listing

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