The title compound, [PdCl(C(14)H(23)N(5))]Cl·0.25H(2)O, is a pseudopolymorph of the previously reported compound [PdCl(C(14)H(23)N(5))]Cl·2H(2)O [de Mendoza et al. (2006 ▶). Acta Cryst. E62, m2934-m2936]. The cationic complex and chloride anion are disordered over two positions each in a 0.584 (4):0.416 (4) ratio. The geometry about the Pd atom is distorted square-planar. The pyrazole rings are almost perpendicular, forming a dihedral angle of 86.6 (6)° to each other, to mitigate steric conflict between their methyl groups.
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http://dx.doi.org/10.1107/S1600536810035427 | DOI Listing |
Acta Crystallogr E Crystallogr Commun
July 2019
Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany.
In the crystal structure of the isostructural title compounds, namely {2,6-bis-[(di--butyl-phosphan-yl)-oxy]-4-hy-droxy-phen-yl}chlorido-palladium(II), [Pd(CHOP)Cl], , and {2,6-bis-[(di--butyl-phosphan-yl)-oxy]-4-hy-droxy-phen-yl}chlorido-platinum(II), [Pt(CHOP)Cl], , the metal centres are coordinated in a distorted square-planar fashion by the POCOP pincer fragment and the chloride ligand. Both complexes form strong hydrogen-bonded chain structures through an inter-action of the OH group in the 4-position of the aromatic POCOP backbone with the halide ligand.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
September 2010
The title compound, [PdCl(C(14)H(23)N(5))]Cl·0.25H(2)O, is a pseudopolymorph of the previously reported compound [PdCl(C(14)H(23)N(5))]Cl·2H(2)O [de Mendoza et al. (2006 ▶).
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
June 2009
In the title compound, [PdCl(C(34)H(33)P(3))]PF(6), the Pd(II) atom adopts a distorted PdP(3)Cl square-planar geometry arising from the P,P',P''-tridentate triphos ligand and a chloride ion.
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