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Bis(3-amino-pyrazine-2-carboxyl-ato-κN,O)diaqua-manganese(II). | LitMetric

Bis(3-amino-pyrazine-2-carboxyl-ato-κN,O)diaqua-manganese(II).

Acta Crystallogr Sect E Struct Rep Online

College of Chemistry & Chemical Engineering, Xianyang Normal University, Xianyang 712000, Shaanxi, People's Republic of China.

Published: September 2010

The Mn(II) atom in the title compound, [Mn(C(5)H(4)N(3)O(2))(2)(H(2)O)(2)], exhibits an octa-hedral geometry comprising the two O atoms and two N atoms from two 3-amino-pyrazine-2-carboxyl-ate ligands, which act as chelating ligands, and two water mol-ecules. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds link adjacent mol-ecules into a three-dimensional network. The mol-ecule lies on a twofold rotation axis.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983285PMC
http://dx.doi.org/10.1107/S1600536810034835DOI Listing

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