Methyl 2-amino-4-(3-chloro-prop-oxy)-5-methoxy-benzoate.

Acta Crystallogr Sect E Struct Rep Online

Published: April 2009

The asymmetric unit of the title compound, C(12)H(16)ClNO(4), contains two crystallographically independent mol-ecules. The benzene rings of the two independent mol-ecules are oriented at a dihedral angle of 88.50 (3)°. Intra-molecular N-H⋯O hydrogen bonds involving the methoxybenzoate carbonyl group in each molecule result in the formation of two planar, six-membered rings, oriented at dihedral angles of 1.39 (3) and 0.68 (3)° with respect to the adjacent benzene rings. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains along the a axis.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977643PMC
http://dx.doi.org/10.1107/S1600536809011374DOI Listing

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