4-Chloro-2-[(E)-2-(4-methoxy-phen-yl)ethyl-imino-meth-yl]phenol.

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

Published: April 2009

AI Article Synopsis

  • The Schiff base compound has the chemical formula C(16)H(16)ClNO(2).
  • Both the 2-(4-methoxy-phenyl)ethyl and 4-chloro-2-(imino-methyl)phenol sections are nearly flat, with a small deviation in their geometry.
  • A hydrogen bond exists between the hydroxyl group and the imino nitrogen atom, indicating a strong intermolecular interaction.

Article Abstract

In the title Schiff base, C(16)H(16)ClNO(2), the 2-(4-methoxy-phen-yl)ethyl (CH(3)OC(6)H(4)CH(2)CH(2)-; r.m.s. deviation = 0.10 Å) and 4-chloro-2-(imino-meth-yl)phenol (N=CHC(6)H(3)ClOH; r.m.s. deviation = 0.01 Å) portions are both essentially planar, the two parts being inclined at an angle of 61.8 (1)°. The hydroxy group forms a hydrogen bond to the imino N atom.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977750PMC
http://dx.doi.org/10.1107/S1600536809013348DOI Listing

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