[μ-N,N'-Bis(diphenyl-phosphinometh-yl)benzene-1,4-diamine-κP:P']bis-[(2,2'-bipyridine-κN,N')silver(I)] bis-(per-chlorate) acetone disolvate.

Acta Crystallogr Sect E Struct Rep Online

School of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004, People's Republic of China.

Published: April 2009

The title complex, [Ag(2)(C(10)H(8)N(2))(2)(C(32)H(30)N(2)P(2))](ClO(4))(2)·2CH(3)COCH(3), is a centrosymmetric dimer with pairs of Ag(I) atoms bridged by N,N'-bis-(diphenyl-phosphinometh-yl)ben-zene-1,4-diamine ligands. In addition, each Ag(I) atom is coordin-ated by one chelating 2,2'-bipyridine ligand, giving a distorted trigonal coordination environment.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977627PMC
http://dx.doi.org/10.1107/S1600536809014871DOI Listing

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