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(E)-4-(β-d-Allopyran-os-yloxy)cinnamyl 4-bromo-phenyl ketone ethanol solvate. | LitMetric

(E)-4-(β-d-Allopyran-os-yloxy)cinnamyl 4-bromo-phenyl ketone ethanol solvate.

Acta Crystallogr Sect E Struct Rep Online

College of Chemistry, Sichuan University, Chengdu 610064, People's Republic of China.

Published: July 2009

The title compound, C(21)H(21)BrO(7)·C(2)H(6)O, was synthesized by the Claisen-Schimidt reaction of helicid (systematic name: 4-formyl-phenyl-β-d-allopyran-oside) with 4-bromo-aceto-phenone in ethanol. The pyran ring adopts a chair conformation. In the crystal structure, mol-ecules are linked into a three-dimensional network by inter-molecular O-H⋯O hydrogen bonds.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977370PMC
http://dx.doi.org/10.1107/S1600536809029687DOI Listing

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