Bis(1,10-phenanthroline-κN,N')(sulfato-κO,O')nickel(II) ethane-1,2-diol solvate.

Acta Crystallogr Sect E Struct Rep Online

Department of Applied Chemistry, Nanjing College of Chemical Technology, Nanjing, Jiangsu Province, People's Republic of China.

Published: July 2009

In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(2)H(6)O(2), the coordination polyhedron around the Ni(2+) ion is a distorted octahedron, with four N atoms from two phenanthroline groups and two O atoms from a bidentate sulfate ligand. The Ni(2+) ion lies on a special position of site symmetry 2. Inter-molecular O-H⋯O hydrogen bonds help to stabilize the structure. The OH group of the ethane-1,2-diol solvent is disordered over two positions with equal occupancy.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977342PMC
http://dx.doi.org/10.1107/S1600536809026269DOI Listing

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