AI Article Synopsis
- - The compound [Ru(2)(C(14)H(17)O)(2)(CO)(4)] features a crystal structure where each Ru(I) atom is bonded to carbonyl groups and a cyclopentadienyl ring.
- - Two Ru atoms form a binuclear complex connected by bridging carbonyl groups, resulting in four-membered rings positioned at centers of inversion.
- - The Ru-Ru bond distance is 2.7483 (11) Å, indicating a single bond, and the carbonyl groups in this structure are oriented trans to each other.
Article Abstract
In the crystal structure of the title compound, [Ru(2)(C(14)H(17)O)(2)(CO)(4)], each Ru(I) atom is connected to one end-on and two bridging carbonyl groups and one cyclo-penta-dienyl ring. The two Ru atoms are connected into binuclear complexes via two bridging carbonyl groups, forming four-membered rings which are located on centres of inversion. The Ru-Ru distance of 2.7483 (11) Å corresponds to a single bond. The two carbonyl groups in these binuclear complexes are trans-oriented.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977131 | PMC |
| http://dx.doi.org/10.1107/S1600536809026075 | DOI Listing |
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