AI Article Synopsis
- The compound is a binuclear metal-carbonyl complex with a Ru-Ru single bond of 2.7511 Å.
- Each Ru atom is surrounded by two bridging carbonyls, one terminal carbonyl, and one η(5)-cyclo-penta-dienyl group.
- The structure has a trans conformation, with parallel cyclo-penta-dienyl ring planes and weak C-H⋯O hydrogen bonds.
Article Abstract
The title compound, [Ru(2)(C(13)H(15)S)(2)(CO)(4)], is a centrosymmetric binuclear metal-carbonyl complex containing an Ru-Ru single bond [2.7511 (8) Å]. Each Ru(I) atom is coordinated by two bridging carbonyl ligands, one terminal carbonyl ligand and one η(5)-cyclo-penta-dienyl group. The complex has a trans conformation and the two cyclo-penta-dienyl ring planes are parallel. The crystal structure involves weak C-H⋯O hydrogen bonds.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977155 | PMC |
| http://dx.doi.org/10.1107/S1600536809026063 | DOI Listing |
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