The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal-bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds is significantly longer than the other.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977257PMC
http://dx.doi.org/10.1107/S1600536809025641DOI Listing

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